Nacci Angelo

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Curriculum di Nacci Angelo

Prof. Angelo Nacci Chemistry Department, University of Bari via Orabona 4, I-70126 BARI, ItalyTel.: (++39) 080 5442499; Telefax: (++39) 080 5442129 e-mail: Questo indirizzo email è protetto dagli spambots. È necessario abilitare JavaScript per vederlo.

PERSONAL DATA:Born in Ostuni (Italy), on October 10, 1964; Italian citizen.

CURRICULUM VITAE

EDUCATION:

• 1990, Doctorate Degree (equivalent to Master) in Chemistry Sciences (magna cum laude) • 1994, PhD from Bari University (Italy) working in the field of organometallic chemistry • 1994 he became researcher for the Chemistry Dept. of Bari.• 2001 visiting researcher - TUM University of Munich (Germany) • 2005, Associate Professor • Research interests are focused on the following topics: i) organometallic chemistry and green synthesis in ionic liquids or other eco-friendly solvents; ii) C-C bond formation by using organo-copper reagents; iii) organic transformations promoted by aminium salts, iv) CO2 capture and valorization.

PROFESSIONAL SOCIETIES:

Italian Chemical Society, since 1993 to present.

Pubblicazioni di Nacci Angelo

 

62. M. Casiello, F. Iannone, P. Cotugno, A. Monopoli, N. Cioffi, F. Ciminale, A. M. Trzeciak, A. Nacci Copper(II)-catalysed oxidative carbonylation of aminols and amines in water: a direct access to oxazolidinones, ureas and carbamates J. Mol. Catal.. A: Chemical, 2015, 407, 8–14

 61.  A Monopoli, P Cotugno, CG Zambonin, F Ciminale, A Nacci  Highly selective palladium–benzothiazole carbene-catalyzed allylation of active methylene compounds under neutral conditions   Beilstein Journal of Organic Chemistry 11 (1), 2015, 994-999

 60.  P Cotugno, A Monopoli, F Ciminale, A Milella, A Nacci  Palladium‐Catalyzed Cross‐Coupling of Styrenes with Aryl Methyl Ketones in Ionic Liquids: Direct Access to Cyclopropanes  Angew. Chemie Int. Ed. 2014, 53, 13563 –13567

 59.   A. Monopoli, P. Cotugno, F. Iannone, F. Ciminale, M.M. Dell'Anna, P. Mastrorilli, A. Nacci Ionic‐Liquid‐Assisted Metal‐Free Oxidative Coupling of Amines To Give Imines. European Journal of Organic Chemistry 2014, 27, 5925-5931

58.  A Monopoli, C D Calvano, Nacci A, F Palmisano. Boronic acid chemistry in MALDI MS: a step forward in designing a reactive matrix with molecular recognition capabilities.           Chemical Communications, 2014, vol. 50, p. 4322-4324

 57.   A. Monopoli, A. Afzal, C. di Franco, N. Ditaranto, N. Cioffi, Nacci A, P. Cotugno, L. Torsi.  Design of novel indium oxide supported gold nanocatalysts and their application in homocoupling of arylboronic acids J. Mol. Catal.. A: Chemical, 2014, vol. 386, p. 101-107

 56.  P. Cotugno, A. Monopoli, Nacci A, C. G. Zambonin, C. D. Calvano. MALDI-MS and HILIC ESI-MS/MS as versatile tools for detection of monoethanolamine degradation products in a real post-combustion carbon dioxide capture plant. ENERGY & FUELS, 2014,  28, 1295-1303

 55) P. Cotugno, M. Casiello, Nacci A, P. Mastrorilli, M. M. Dell’Anna, A. Monopoli. Suzuki coupling of iodo and bromoarenes catalyzed by chitosan-supported Pd-nanoparticles in ionic liquids. J. Organomet. Chem., 2014, 752, 1-5.

 54.  Casiello M, Monopoli A, Cotugno P, Milella A, Dell’Anna MM, Ciminale F, Nacci A Copper(II) chloride-catalyzed oxidative carbonylation of glycerol to glycerol carbonate. J. Mol. Catal.. A: Chemical, 2014, 381 99– 106

 53. Pilolli R, Ditaranto N, Monopoli A, Nacci A, Palmisano F, Sabbatini L, Cioffi N  Designing functionalized gold surfaces and nanostructures for Laser Desorption Ionisation Mass Spectrometry. VACUUM, 2014, 100, p. 78-83

 52. P. Mastrorilli, A. Monopoli, M. M. Dell’Anna, M. Latronico, P. Cotugno, A. Nacci. Ionic Liquids in Palladium-Catalyzed Cross-Coupling Reactions. Organomet. Chem. 2013, DOI: 10.1007/3418_2013_64

51. P. Giannoccaro, M. Casiello, A. Milella, A. Monopoli, P. Cotugno, A. Nacci.  Synthesis of 5-membered cyclic carbonates by oxidative carbonylation of 1,2-diols promoted by copper halides. J. Mol. Catal. A: Chemical, 2012, 365, 162-171.                                                                            

50.  A. Monopoli, P. Cotugno, G. Palazzo, N. Ditaranto,B. Mariano, N. Cioffi, F. Ciminale, A. Nacci. Ullmann Homocoupling Catalyzed by Gold Nanoparticles in Water and Ionic Liquid.  Adv. Synth. & Catal., 2012, 354, 2777-2788                                                                                  

49 .A. Monopoli, P. Cotugno, M. Cortese, C. D. Calvano, F. Ciminale, A. Nacci. Selective N-alkylation of Arylamines with Alkyl Chloride in Ionic Liquids: Scope and Applications. Eur. J. Org. Chem. 2012, 3105–3111                                                                                              

48. Cotugno, A. Monopoli, F. Ciminale, N. Cioffi, A. Nacci. Pd-nanoparticles catalyzed one-pot sequential Heck and Suzuki couplings of bromo-chloroarenes in ionic liquids and water . Org. & Biomol. Chem., 2012, 10, 808-813                                                                                  

47.  A. Nacci, N. Cioffi Special issue: Nano-catalysts and nano-technologies for green organic synthesis. Molecules, Vol. 16, Issue 2, 2011, pp. 1452-1453       

46. Antonio Monopoli, Angelo Nacci, Vincenzo Calò, Francesco Ciminale, Pietro Cotugno, Annarosa Mangone, Lorena Carla Giannossa, Pietro Azzone, Nicola Cioffi . Palladium/zirconium Oxide Composite as Highly Recyclable Nanocatalysts for C-C Coupling Reactions in Water. Molecules.  2010, 15, 4511-4525

45. A. Monopoli; V. Calò, F. Ciminale, P. Cotugno, C. Angelici, N. Cioffi, A. Nacci. Glucose as a Clean and Renewable Reductant in the Pd-Nanoparticle-Catalyzed Reductive Homocoupling of Bromo- and Chloroarenes in Water. J. Org. Chem.  2010, 75, 3908–3911

44. Vincenzo Calò, Angelo Nacci,Antonio Monopoli, Pietro Cotugno.Heck Reactions with Palladium Nanoparticles in Ionic Liquids: Coupling of Aryl Chlorides with Deactivated Olefins. Angew. Chem. Int. Ed. 2009, 48, 6101 –6103

43. Vincenzo Calò, Angelo Nacci,Antonio Monopoli, Pietro Cotugno.Pd-Nanoparticles-Catalyzed Ullmann-Reactions in Ionic Liquids Using Aldehydes as theReductants: Scope and Mechanism. Chem. Eur. J. 2009, 15, 1272 – 1279.

42. Vincenzo Calò, Angelo Nacci,Antonio Monopoli, Anna Damascelli, Eliana Ieva and Nicola Cioffi.Palladium-nanoparticles Catalysed Hydrodehalogenation of Aryl Chlorides in Ionic Liquids. Journal of Organometallic Chemistry,2007, 692, 4397–4401.

41. Vincenzo Calò, Angelo Nacci, Antonio Monopoli, Valentina Ferola. Palladium-catalyzed Heck arylations of allyl alcohols in ionic liquids: remarkable base effect on the selectivity.Journal of Organic Chemistry,2007, 72, 2596-2601.

40. N. Cioffi, M. Faticanti, N. Ditaranto, S. De Rossi, L. Traversa, A. Monopoli, A. Nacci, L. Torsi , L. Sabbatini. Analytical characterisation of Pd/ZrO2 composite nanoparticles employed in heterogeneous catalysis. Current Nanoscience,2007, 3, 121-127.

39. Vincenzo Calò, Angelo Nacci, Antonio Monopoli. Effects of Ionic Liquids on Pd-Catalysed Carbon-Carbon Bond Formation.  European Journal of Organic Chemistry,2006,3791-3802.

38. Vincenzo Calò, Angelo Nacci, Antonio Monopoli. Pd–benzothiazol-2-ylidene complex in ionic liquids: Efficient catalyst for carbon–carbon coupling reactions. Journal of Organometallic Chemistry,2005, 690,5458–5466.

37. Vincenzo Calò, Angelo Nacci, Antonio Monopoli, Floriana Montingelli. Pd-Nanoparticles as Efficient Catalysts for Suzuki and Stille Coupling Reactions of Aryl Halides in Ionic Liquids.  J. Org. Chem. 2005, 70, 6040-6044.

36. Vincenzo Calò, Angelo Nacci, Antonio Monopoli, Eliana Ievaand Nicola Cioffi          Cu Nanoparticles Catalyzed Heck Reaction in Ionic Liquids. Organic Letters, 2005, 7, 617-620.

35. Francesco Ciminale, Luigi Lopez, Angelo Nacci, Lucia D’Accolti and Floriana Vitali. Aminium Hexachloroantimonate Salts as Latent Sources of Antimony Pentachloride in Pinacolic Rearrangement of Vicinal Diols. European Journal of Organic Chemistry, 2005, 1597-1603

34. Vincenzo Calo`, Angelo Nacci, Antonio Monopoli, Antonio Fornaro, Luigia Sabbatini, Nicola Cioffi and Nicoletta Ditaranto. Heck Reaction Catalyzed by Nanosized Palladium on Chitosan in Ionic Liquids. Organometallics, 2004, 23, 5154-5158.

33. Vincenzo Calò, Angelo Nacci, Antonio Monopoli. Regio- and Stereo-Selective Carbon-Carbon Bond Formation in Ionic Liquids.Journal of Molecular catalysis A: Chemicals, 2004, 214, 45-56.

32. Vincenzo Calo´, Angelo Nacci, Antonio Monopoli, Antonia Detomaso, Patrizia IliadePd Nanoparticle Catalyzed Heck Arylation of 1,1-Disubstituted Alkenes in Ionic Liquids. Study on Factors Affecting the Regioselectivity of the Coupling Process. Organometallics, 2003, 22, 4193-4197

31. Vincenzo Calò,FernandoScordari, Angelo Nacci, Emanuela Schingaro, Lucia D’Accolti and Antonio Monopoli. Stereoselective Synthesis of Tetrasubstituted 2,3-Dihydrofurans by One-Step Cyclization of b-Ketosulfides of Benzothiazole and Aldehydes in Ionic Liquids. Journal of Organic Chemistry, 2003, 68, 4406-4409.

30. Vincenzo Calò, Angelo Nacci, Antonio Monopoli, Stefania Laera and Nicola Cioffi. Pd Nanoparticles Catalyzed Stereospecific Synthesis of b-Aryl Cinnamic Esters in Ionic Liquids. Journal of Organic Chemistry, 2003, 68, 2929-2933.

29. Vincenzo Calò, Angelo Nacci, Antonio Monopoli and Michele Spinelli. Arylation of Allylic Alcohols in Ionic Liquids by a Pd-Benzothiazole Carbene Complex.European Journal of Organic Chemistry, 2003, 1382-1385.

28. Francesco Ciminale, Luigi Lopez, Gianluca M. Farinola, Stefano Sportelliand Angelo Nacci. Acid Catalysis in Aminium Hexachloroantimonates-Induced Cyclodimerization of 1-Aryl-1-phenylethylenes. European Journal of Organic Chemistry, 2002, 3850-3854.

27. Vincenzo Caló, Angelo Nacci, Antonio Monopoli and Antonello Fanizzi. Cyclic Carbonates Formation from Carbon Dioxide and Oxiranes in Tetrabutylammonium Halides as Solvents and Catalysts. Organic Letters, 2002, 4(15), 2561-2563.

26. Vincenzo Calò, Potenzo Giannoccaro, Angelo Nacci and Antonio Monopoli. Pd-benzothiazole Carbene Catalysed Carbonylation of Aryl Halides in Ionic liquids. Journal of Organometallic Chemistry, 2002, 645/1-2, 152-157.

25. Vincenzo Calò, Angelo Nacci.Influence of Ionic Liquids on Pd-Catalysed Carbon-Carbon Bond FormationZ. Naturforsch, 2001, 56a, 702-706.

24. Vincenzo Calò, Angelo Nacci, Luigi Lopez and Annalisa Napola.Arylation of a-Substituted Acrylates in Ionic Liquids Catalyzed by a Pd-Benzothiazole Carbene Complex. Tetrahedron Letters, 2001, 42, 4701-4703.

23. Vincenzo Calò, Angelo Nacci, Antonio Monopoli, Luigi Lopez and Anna di Cosmo.Heck Reaction of b-Substituted Acrylates in Ionic Liquids Catalyzed by a Pd-Benzothiazole Carbene Complex. Tetrahedron, 2001, 57, 6071-6077.

22. Vincenzo Calò, Angelo Nacci, Luigi Lopez and Vito Luigi Lerario. Stereoselective Synthesis of Electrophilic Spirocyclopropanes in Ionic Liquids. Tetrahedron Letters, 2000, 41, 8977-8980.

21. Vincenzo Calò, Angelo Nacci, Luigi Lopez and Nicola Mannarini. Heck Reaction in Ionic Liquids Catalyzed by a Pd-Benzothiazole Carbene Complex.  Tetrahedron Letters, 2000, 41, 8973-8976.

20. Vincenzo Caló, Roberta Del Sole, Angelo Nacci, Emanuela Schingaro and Fernando Scordari. Synthesis and Crystal Structure of Bis(2,3-dihydro-3-methylbenzothiazole-2-ylidene)palladium(II) Diiodide: the First Palladium Complex with Benzothiazole Carbene Ligands Suitable  for Homogeneous Catalysis. European Journal of Organic Chemistry, 2000, 869-871.

19. Maria M. Dell’anna, Pietro Mastrorilli, Francesco Cosimo Nobile, Maria R. Taurino, Vincenzo Calò, Angelo Nacci. Regioselective aerobic oxidation of bis-sulfides into monosulfoxides. Journal of Molecular Catalysis A: Chemical, 2000, 151, 61-69.

18. Leonardo di Nunno, Carlo Franchini, Angelo Nacci, Antonio Scilimati and Maria Stefania Sinicropi. Baker’s yeast-induced asymmetric reduction of a-ketosulfides: synthesis of optically active 1-(benzothiazol-2-ylsulfanyl)-2-alkanols, 2-alkanols, and thiiranes.       Tetrahedron: Asymmetry, 1999, 10, 1913-1926.

17. Francesco Ciminale, Antonella Ciardo,Salvatore Francioso and Angelo Nacci.Oxidative Activation in Aromatic Substitutions. Reactions of N,N-dimethylanilines with     Secondary Anilines Promoted by Thallium Triacetate.Journal of Organic Chemistry, 1999, 64, 2459-2464.

16. Vincenzo Calò, Angelo Nacci.Stereoselective Synthesis of 1,4-Dienes by Chelation-controlled Reduction of Benzothiazole  beta-Oxosulfides.  Tetrahedron Letters, 1998, 39, 3825-3828.

15. Luigi Lopez, Gianluca M. Farinola, Angelo Nacci, Stefano Sportelli.Monodeoxygenation of Spiro Adamantane-1,2-Dioxetanes Induced by Aminium Salt.Tetrahedron, 1998, 54, 6939-6946.

14. Vincenzo Calò, Angelo Nacci and Angela Volpe.Synthesis of 2-oxo-oxazolidines and -thiazolidines from the corresponding 2-thioxo compounds. Gazzetta Chimica Italiana, 1997, 127, 283-285.

13. Luigi Lopez, Gianluca M. Farinola, Vincenza Paradiso, Giuseppe Mele and Angelo Nacci. Reactions on (R) and (S) -1,1,2-Triphenyl-1,2-Ethandiols Induced by Aminium Salts and Protic Acids. Solvent Effect.Tetrahedron, 1997, 53, 10817-10826.

12. Vincenzo Calò, Angelo Nacci, Vito Fiandanese and Angela Volpe. Reaction of Heterocyclic Allyl Sulphides with Ethyl Diazoacetate: a Simple Method for the            Synthesis of Conjugated Dienoic Esters.Tetrahedron Letters, 1997, 38, 3289-3290.

11. Luigi Lopez, Giuseppe Mele, Vincenza Paradiso, Angelo Nacci and Piero Mastrorilli.Reactions of a-Ionone Oxide with Aminium Salts, Brønsted and Lewis Acids. Synthesis of New Therminal Group Synthons.Gazzetta Chimica Italiana, 1996, 126, 725-727.

10. Francesco Ciminale, Luigi Lopez, Vincenza Paradiso, Angelo Nacci.Aminium Salts-Induced Dimerization of a-Methylstyrene and 1-Aryl-1-Phenylethylenes. Solvent Effect.Tetrahedron, 1996, 52, 13971-13980.

9. Vincenzo Calò, Angelo Nacci and Vito Fiandanese.Copper-mediated Regio- and Enantio-selective Cross-coupling of Heterocyclic Allyl Sulphides with Organomagnesium Compounds: A Case of 1,7-Relative Stereogenesis.Tetrahedron, 1996, 52, 10799-10810.

8. Vincenzo Calò, Vito Fiandanese, Angelo Nacci and Angela Volpe.Allylated Ketosulphides of Benzothiazole as Intermediates for Stereoselective Synthesis of Allyl Ketones, Allyl Thiiranes and Dienes. Tetrahedron, 1996, 52, 2155-2166.

7. Vincenzo Calò, Luigi Lopez, Angelo Nacci, Giuseppe Mele.  Aminium Salts Induced Desulphurization of Allyl and Diallyl Thiiranes. Synthesis of Dienes and Trienes.        Tetrahedron, 1995, 51, 8935-8940.

6. Vincenzo Calò, Vito Fiandanese, Angelo Nacci and Antonio Scilimati.Palladium-catalysed Synthesis of a-Diallylated Ketosulphides of Benzothiazole and their Transformation into Diallyl Thiiranes and Trienes. Tetrahedron Letters, 1995, 36, 171-174.

5. Luigi Lopez, Giuseppe Mele, Vito Fiandanese, Cosimo Cardellicchio andAngelo Nacci. Aminium salts catalysed rearrangement ofa-pinene andb-ionone oxides.             Tetrahedron, 1994, 50, 9097-9106.

4. Vincenzo Calò, Vito Fiandanese, Angelo Nacci and Antonio Scilimati. Chelation-controlled chemo-, regio- and enantio-selective synthesis of homoallylic alcohols. Tetrahedron, 1994, 50, 7283-7292.

3. Luigi Lopez, Giuseppe Mele, Angelo Nacci and Luigino Troisi. One-pot conversion of alfa-substituted arylacetaldehydes into alfa-dicarbonyl compounds. Tetrahedron Letters, 1993, 34, 3897-3900.

2. Vincenzo Calò, Vito Fiandanese, Angelo Nacci.Chemoselectivity influenced by coordination in the allylic substitution with organometallics.    Trends in Organic Chemistry, 1993, 4, 479-491. 

1. V.Calò, A. Nacci. Procedimento per la preparazione di 1,3-diossolan-2-oni. Brevetto italiano Nr. ITMI20011344 A del 27/12/2002.

Attività di Ricerca di Nacci Angelo

Research topics:

Prof. Nacci's research topics are focussed on the preparation, analytical characterization and application in organic synthesis of nano- and micro-structured metal catalysts in the form of colloidal dispersion or supported on solid stabilizing matrixes (palladium, copper and gold are the main metals used). The group also boasts a consolidated experience in the field of Green Chemistry, with the development of a wide plethora of eco-friendly synthetic methodologies employing green solvents like ionic liquids, water and micellar systems, together with clean and renewable reagents like monosaccharides, ascorbic acid etc.
The main topics of the group can be summarized as follows: i) innovative synthesis in the field of carbon-carbon bond forming reactions (Heck, Suzuki, Stille, Ullmann etc.), with particular attention to the synthesis of unsymmetrically substituted olefins and arenes, bi- and ter-phenyls, and other useful synthons in pharmaceutical and materials chemistry; (ii) CO2 capture and valorization; (iii) detoxification of polychlorinated biphenyls (PCBS); (iv) synthesis of innovative MALDI matrixes

 

(Italian) Il gruppo di ricerca del Prof. Nacci si occupa da anni della preparazione, caratterizzazione analitica ed applicazione in sintesi organica di catalizzatori metallici nano- e micro-strutturati impiegati sia in forma di dispersione colloidale che supportati su matrici solide stabilizzanti (palladio, rame ed oro sono i principali metalli impiegati). Il gruppo vanta anche una consolidata esperienza nel campo della Green Chemistry, avendo messo a punto una vasta pletora di metodologie sintetiche eco-compatibili che impiegano solventi green come liquidi ionici, acqua e/o sistemi micellari etc., e reagenti puliti e rinnovabili come monosaccaridi, ac. ascorbico etc.

Le principali linee di ricerca del gruppo sono:

i) sintesi innovative nel campo delle reazioni di formazione del legame carbonio-carbonio (tipo Heck, Suzuki, Stille, Ullmann etc.,), con particolare riferimento alla sintesi di olefine ed areni asimmetricamente sostituiti, bifenili, terfenili, etc. utili sintoni in campo farmaceutico ed in quello dei materiali;

ii) processi di cattura e valorizzazione della CO2 (ed altri gas serra);

iii) detossificazione di policlorobifenili (PCB), una classe di inquinanti ritenuti un vera e propria emergenza ambientale;

iv) sintesi di nuovi leganti tiolici per oro nanostrutturato da usare in spettroscopia MALDI.

Programmi ed Appelli di Nacci Angelo